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Abstract The first stars were born from chemically pristine gas. They were likely massive, and thus they rapidly exploded as supernovae, enriching the surrounding gas with the first heavy elements. In the Local Group, the chemical signatures of the first stellar population were identified among low-mass, long-lived, very metal-poor ([Fe/H] < −2) stars, characterized by high abundances of carbon over iron ([C/Fe] > +0.7): the so-called carbon-enhanced metal-poor stars. Conversely, a similar carbon excess caused by first-star pollution was not found in dense neutral gas traced by absorption systems at different cosmic time. Here we present the detection of 14 very metal-poor, optically thick absorbers at redshift z ∼ 3–4. Among these, 3 are carbon-enhanced and reveal an overabundance with respect to Fe of all the analyzed chemical elements (O, Mg, Al, and Si). Their relative abundances show a distribution with respect to [Fe/H] that is in very good agreement with those observed in nearby very metal-poor stars. All the tests we performed support the idea that these C-rich absorbers preserve the chemical yields of the first stars. Our new findings suggest that the first-star signatures can survive in optically thick but relatively diffuse absorbers, which are not sufficiently dense to sustain star formation and hence are not dominated by the chemical products of normal stars. 

ABSTRACT We present the measured gas-phase metal column densities in 155 sub-damped Ly α systems (subDLAs) with the aim to investigate the contribution of subDLAs to the chemical evolution of the Universe. The sample was identified within the absorber-blind XQ-100 quasar spectroscopic survey over the redshift range 2.4 ≤ zabs ≤ 4.3. Using all available column densities of the ionic species investigated (mainly C iv, Si ii, Mg ii, Si iv, Al ii, Fe ii, C ii, and O i; in order of decreasing detection frequency), we estimate the ionization-corrected gas-phase metallicity of each system using Markov chain Monte Carlo techniques to explore a large grid of cloudy ionization models. Without accounting for ionization and dust depletion effects, we find that the H i-weighted gas-phase metallicity evolution of subDLAs is consistent with damped Ly α systems (DLAs). When ionization corrections are included, subDLAs are systematically more metal poor than DLAs (between ≈0.5σ and ≈3σ significance) by up to ≈1.0 dex over the redshift range 3 ≤ zabs ≤ 4.3. The correlation of gas phase [Si/Fe] with metallicity in subDLAs appears to be consistent with that of DLAs, suggesting that the two classes of absorbers have a similar relative dust depletion pattern. As previously seen for Lyman limit systems, the gas phase [C/O] in subDLAs remains constantly solar for all metallicities indicating that both subDLAs and Lyman limit systems could trace carbon-rich ejecta, potentially in circumgalactic environments. 

Abstract Sub-damped Lyman α systems (subDLAs; H i column densities of 19.0 ≤ logN(H i) < 20.3) are rarely included in the cosmic H i census performed at redshifts zabs ≳ 1.5, yet are expected to contribute significantly to the overall H i mass budget of the Universe. In this paper, we present a blindly selected sample of 155 subDLAs found along 100 quasar sightlines (with a redshift path-length ΔX = 475) in the XQ-100 legacy survey to investigate the contribution of subDLAs to the H i mass density of the Universe. The impact of X-Shooter’s spectral resolution on Ly α absorber identification is evaluated, and found to be sufficient for reliably finding absorbers down to a column density of logN(H i) ≥ 18.9. We compared the implications of searching for subDLAs solely using H i absorption versus the use of metal lines to confirm the identification, and found that metal-selection techniques would have missed 75 subDLAs. Using a bootstrap Monte Carlo simulation, we computed the column density distribution function (f(N, X)) and the cosmological H i mass density ($$\Omega _{\rm H\,{\small I}}$$) of subDLAs and compared with our previous work based on the XQ-100 damped Lyman α systems. We do not find any significant redshift evolution in f(N, X) or $$\Omega _{\rm H\,{\small I}}$$ for subDLAs. However, subDLAs contribute 10–20 per cent of the total $$\Omega _{\rm H\,{\small I}}$$ measured at redshifts 2 < z < 5, and thus have a small but significant contribution to the H i budget of the Universe.